[en] Fully bio- and CO2-sourced non-isocyanate polyurethanes (NIPUs) were synthesized by reaction of carbonated soybean oil (CSBO) either with biobased short diamines or amino-telechelic oligoamides derived from fatty acids to achieve respectively thermoset or thermoplastic NIPUs. Biobased carbonated vegetable oils were first obtained by metal-free coupling reactions of CO2 with epoxidized soybean oils under supercritical conditions (120 °C, 100 bar) before complete characterization by FTIR, 1H NMR, and electrospray ionization mass spectroscopy (ESI-MS). In a second step, biobased NIPUs were produced by melt-blending of the so-produced cyclocarbonated oil with the biobased aminated derivatives. The thermal and mechanical properties of resulting polymers were found to be depending on the cyclocarbonated vegetable oil/amine ratio. More precisely, short diamines and CSBO led to the formation of cross-linked NIPUs, and the resulting tensile and thermal properties were poor. In contrast, elastomeric NIPUs derived from oligoamides and CSBO exhibited a better rigidity, an improved elongation at break (εr up to 400%), and a higher thermal stability (T95 wt% > 350 °C) than those of starting oligoamides. These results are impressive and highlight the potentiality of this environmental friendly approach to prepare renewable NIPU materials of high performances.
Research center :
Center for Education and Research on Macromolecules (CERM)
Disciplines :
Materials science & engineering Chemistry
Author, co-author :
Poussard, Loïc; University of Mons (UMons), Center of Innovation and Research in Materials & Polymers (CIRMAP), Laboratory of Polymeric and Composite Materials (LPCM), Belgium
Mariage, J.; University of Mons (UMons), Center of Innovation and Research in Materials & Polymers (CIRMAP), Laboratory of Polymeric and Composite Materials (LPCM), Belgium
Grignard, Bruno ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Detrembleur, Christophe ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Jérôme, Christine ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Calberg, Cédric ; University of Liège (ULg), Department of Applied Chemistry, Laboratory of Industrial Chemistry
Heinrichs, Benoît ; University of Liège (ULg), Department of Applied Chemistry, Laboratory of Industrial Chemistry
De Winter, Julien; University of Mons-Hainaut (UMH), Organic Synthesis and Mass Spectrometry Laboratory
Gerbaux, Pascal; University of Mons-Hainaut (UMH), Organic Synthesis and Mass Spectrometry Laboratory
Raquez, Jean-Marie; University of Mons (UMons), Center of Innovation and Research in Materials & Polymers (CIRMAP), Laboratory of Polymeric and Composite Materials (LPCM), Belgium
Bonnaud, Leila; University of Mons (UMons), Center of Innovation and Research in Materials & Polymers (CIRMAP), Laboratory of Polymeric and Composite Materials (LPCM), Belgium
Dubois, Philippe; University of Mons (UMons), Center of Innovation and Research in Materials & Polymers (CIRMAP), Laboratory of Polymeric and Composite Materials (LPCM), Belgium
Language :
English
Title :
Non-isocyanate polyurethanes from carbonated soybean oil Using monomeric or oligomeric diamines To achieve thermosets or thermoplastics
Publication date :
22 March 2016
Journal title :
Macromolecules
ISSN :
0024-9297
eISSN :
1520-5835
Publisher :
American Chemical Society (ACS), Washington, United States - District of Columbia
Volume :
49
Issue :
6
Pages :
2162-2171
Peer reviewed :
Peer Reviewed verified by ORBi
Funders :
The Walloon Region in the frame of the CO2Green program F.R.S.-FNRS - Fonds de la Recherche Scientifique [BE]
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