The next step for Rosetta ROSINA/DMFS data of comet 67P/Churyumov-Gerasimenko: the search for semi-volatiles species.

Using data from Rosetta/ROSINA's Double Focusing Mass Spectrometer (DFMS), a zoo of neutral molecules have been discovered in the coma of 67P/Churyumov-Gerasimenko, which led to a wealth of new insights regarding the comet itself, its formation and the early history of our Solar System.A comprehensive understanding of the overall comet composition requires information on all species involved i.e. the volatiles, semi-volatiles and refractories in the coma. However, while ROSINA targets volatiles and GIADA, MIDAS and COSIMA studied refractories, no instrument on Rosetta provides measurements specifically of semi-volatiles. In some circumstances, ROSINA/DFMS may provide at least some information on semi-volatiles in the coma. As semi-volatile species are progressively released from the grains into the gas coma (their release depends on cometocentric distance and grain size), they can be identified if the abundance ratio of a candidate semi-volatile species (or a fragment thereof) to a volatile species increases as a function of distance from the nucleus. This constitutes a so-called distributed source in the coma.With a mass spectrometer like DFMS, one does not detect neutral coma species, but rather the ionized products thereof after electron impact ionization. A major difficulty is assigning the observed ions to parent neutrals. As semi-volatile species have a low abundance, sum spectra obtained through accumulation of individual DFMS spectra can improve the signal-to-noise ratio in order to provide decisive information for identification. Accurate sum spectra can only be obtained provided all instrument-dependent effects are accounted for.This contribution focuses on the procedure used to create sum spectra and presents some typical results.