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＜departmental bulletin paper＞
Reaction Products of Triose Reductone with Some Amino Acids

Creator
Creator Name
大村, 浩久
Omura, Hirohisa
Affiliation
Affiliation Name
九州大学農学部食糧化学教室
Laboratory of Food Chemistry, Department of Food Science and Technology, Kyushu University
Creator Name
井上, 譲
Inoue, Yuzuru
Affiliation
Affiliation Name
全農飼料中央研究所
The central research of feed, National Federation of Agricultural Cooperative Associations
Author PID
L001825
Creator Name
江藤, 正義
Affiliation
Affiliation Name
九州大学農学部食糧化学教室
Creator Name
曽, 耀崑
Tseng, Yaw-Kun
Affiliation
Affiliation Name
中国文化学院家政学研究所 : 嘉義農業専科学校 : 訪問研究員
Chinese Culture University : National Chiayi Institute of Agriculture : Visiting Scholar
Creator Name
篠原, 和毅
Shinohara, Kazuki
Affiliation
Affiliation Name
九州大学農学部食糧化学教室
Laboratory of Food Chemistry, Department of Food Science and Technology, Kyushu University
Language
Japanese
Publisher
九州大學農學部
Faculty of Agriculture, Kyushu University
Date
1974-09
Source Title
Science bulletin of the Faculty of Agriculture, Kyushu University
Vol
29
Issue
1/2
First Page
61
Last Page
70
Publication Type
Version of Record
Access Rights
open access
JaLC DOI
https://doi.org/10.15017/23179
Related DOI
九州大學農學部學藝雜誌 || 29(1-2) || p61-70
Science bulletin of the Faculty of Agriculture, Kyushu University || 29(1-2) || p61-70
http://www.agr.kyushu-u.ac.jp/
Related URI
九州大學農學部學藝雜誌 || 29(1-2) || p61-70
Science bulletin of the Faculty of Agriculture, Kyushu University || 29(1-2) || p61-70
http://www.agr.kyushu-u.ac.jp/
Relation
九州大學農學部學藝雜誌 || 29(1-2) || p61-70
Science bulletin of the Faculty of Agriculture, Kyushu University || 29(1-2) || p61-70
http://www.agr.kyushu-u.ac.jp/

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Details

Record ID
23179
Peer-Reviewed
Unrefereed
Subject Terms
トリオースレダクトン
アミノ酸
グリシン
ロイシン
メチオニン
フェニルアラニン
反応生成物
調製分離
元素分析
融点
ペーパークロマトグラム
紫外吸収スペクトル
赤外吸収スペクトル
ポーラログラム
NMRスペクトル
ISSN
0368-6264
NCID
AN0005519X
Notes
Condensation product of triose reductone with glycine, leucine, methionine and phenylalanine were prepared with yielding of about 40-50%. Their properties were explained by estimating elementary analysis, melting point, paper chromatogram, polarogram and UV-, IR- and NMR-spectra. For paper chromatography, butanol·acetic acid·water and ethanol.water are fairly suitable as solvent. Absorption peak was estimated at 305～315 nm in acid and neutral media and at 340～345 nm in alkaline medium. The peak was maintained in the former, but decreased in the latter, indicating unstability of TR-AA in alkaline medium. In IR-spectra, common typical peaks were observed at 3400 cm^-1 (NH), 2400 cm^-1 (enolic OH), 1720 cm^-1 (CO of carbonic acid) and 1650 cm^-1 (CO of aldehyde), coinciding with literature. Porlarograms of TR and TRAA was estimated at about +0.2 V of half-wave potential, but with different waveheight. By detailed investigation on NMR-spectra, chemical structure of TR-AA was demonstrated.
トリオースレダクトンとグリシン,ロイシン,メチオニンおよびフェニルアラニンとを等モルに反応させ,反応生成物を結晶状に調製分離した.さらにこれらについて,元素分析,融点のほかペーパークロマトグラム,紫外吸収スペクトル,赤外吸収スペクトル,ポーラログラムおよびNMRスペクトルを求め,それらの諸性質を検討し,構造を確認した.
Created Date 2012.07.25
Modified Date 2022.11.11

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