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https://hdl.handle.net/2440/132588
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Type: | Journal article |
Title: | Key to C₂ production: selective C-C coupling for electrochemical CO₂ reduction on copper alloy surfaces |
Other Titles: | Key to C(2)production: selective C-C coupling for electrochemical CO(2) reduction on copper alloy surfaces |
Author: | Zhi, X. Jiao, Y. Zheng, Y. Qiao, S.-Z. |
Citation: | Chemical Communications, 2021; 57(75):9526-9529 |
Publisher: | Royal Society of Chemistry |
Issue Date: | 2021 |
ISSN: | 1359-7345 1364-548X |
Statement of Responsibility: | Xing Zhi,, Yan Jiao, Yao Zheng and Shi-Zhang Qiao |
Abstract: | The C–C coupling kinetic variations are observed on Cu alloys with Pt, Pd, or Au surface sites. The OC–COH coupling is kinetically more favorable than OC–CHO coupling, which originates from increased reactivity of adsorbed *CO species. Linear energy relations for C–C association/dissociation could simplify the energetic evaluation for C2 production. |
Rights: | This journal is © The Royal Society of Chemistry 2021 |
DOI: | 10.1039/d1cc03796j |
Grant ID: | http://purl.org/au-research/grants/arc/DP190103472 http://purl.org/au-research/grants/arc/FT190100636 http://purl.org/au-research/grants/arc/FL170100154 |
Published version: | http://dx.doi.org/10.1039/d1cc03796j |
Appears in Collections: | Chemistry publications |
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