Reaction of ketones with the organotitanium oxide [{TiCp*(mu-O)}3(mu3-CMe)] via the hydride-vinylidene [{TiCp*(mu-O)}3(mu-C=CH2)(H)] intermediate.
Identifiers
Permanent link (URI): http://hdl.handle.net/10017/63474DOI: 10.1039/A709194J
ISSN: 1359-7345
Date
1998Academic Departments
Universidad de Alcalá. Departamento de Química Orgánica y Química Inorgánica
Teaching unit
Unidad Docente Química Inorgánica
Funders
Dirección General de Investigación Científica y Técnica
Bibliographic citation
Chemical Communications, 1998, v. 6, p. 691-692
Project
info:eu-repo/grantAgreement/DGICYT//PB93-0476/ES
Document type
info:eu-repo/semantics/article
Version
info:eu-repo/semantics/aceptedVersion
Rights
Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)
© Royal Society of Chemistry
Access rights
info:eu-repo/semantics/openAccess
Abstract
Thermal and/or photochemical treatment of [{TiCp*(m-O)}3(m3-CMe)] 1 (Cp* = h5-C5Me5) with organic ketones affords the new oxo derivatives [{TiCp*(m-O)}3(m-C=CH2)(OCHRR';)] (R = R'; = Me 2, Ph 3; R = Ph, R'; = Me 4, Et 5); these reactions take place by insertion of the ketones CO group into the Ti-H bond of the in situ formed [{TiCp*(m-O)}3(m-CCH2)(H)] intermediate.
Files in this item
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Galakhov_Reaction_ChemComm_1998.pdf | 884.4Kb |
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Files | Size | Format |
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Galakhov_Reaction_ChemComm_1998.pdf | 884.4Kb |
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