Determination of the potential of zero charge of Pt/CO electrodes using an impinging jet system
Por favor, use este identificador para citar o enlazar este ítem:
http://hdl.handle.net/10045/109822
Título: | Determination of the potential of zero charge of Pt/CO electrodes using an impinging jet system |
---|---|
Autor/es: | Boronat-González, Ana | Herrero, Enrique | Feliu, Juan M. |
Grupo/s de investigación o GITE: | Electroquímica de Superficies |
Centro, Departamento o Servicio: | Universidad de Alicante. Departamento de Química Física | Universidad de Alicante. Instituto Universitario de Electroquímica |
Palabras clave: | Platinum single-crystal electrodes | Potential of zero charge | Interphase properties | Adsorbed CO | Impinging jet system |
Área/s de conocimiento: | Química Física |
Fecha de publicación: | nov-2020 |
Editor: | Springer Nature |
Cita bibliográfica: | Journal of Solid State Electrochemistry. 2020, 24: 2871-2881. https://doi.org/10.1007/s10008-020-04654-7 |
Resumen: | In this manuscript, the potential of zero charge (pzc) of platinum single-crystal electrodes has been determined using the impinging jet system and recording the transient associated with the interphase formation. Initially, the Pt(111), Pt(110), and Pt(100) electrodes covered with CO were used. To demonstrate the validity of the procedure, the values obtained for the pzc of these electrodes were compared with those previously reported in the literature and also with those expected from work function changes. An excellent agreement has been found. After that, the values for the pzc of the stepped surfaces having (111) terraces and (110) steps were determined. For these surfaces, the pzc initially diminishes as the step density increases, in accordance with the expected diminution of the work function due to the Smoluchowski effect on the step site. However, for the shorter terraces, the pzc value increases with the step density, probably because of step dipole-dipole coupling due to the presence of a CO layer on the electrode. |
Patrocinador/es: | This work has been financially supported by MINECO-FEDER (Spain) through project CTQ2016-76221-P. |
URI: | http://hdl.handle.net/10045/109822 |
ISSN: | 1432-8488 (Print) | 1433-0768 (Online) |
DOI: | 10.1007/s10008-020-04654-7 |
Idioma: | eng |
Tipo: | info:eu-repo/semantics/article |
Derechos: | © Springer-Verlag GmbH Germany, part of Springer Nature 2020 |
Revisión científica: | si |
Versión del editor: | https://doi.org/10.1007/s10008-020-04654-7 |
Aparece en las colecciones: | INV - EQSUP - Artículos de Revistas |
Archivos en este ítem:
Archivo | Descripción | Tamaño | Formato | |
---|---|---|---|---|
Boronat-Gonzalez_etal_2020_JSolidStateElectrochem_final.pdf | Versión final (acceso restringido) | 1,59 MB | Adobe PDF | Abrir Solicitar una copia |
Todos los documentos en RUA están protegidos por derechos de autor. Algunos derechos reservados.