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Morfologia e cristalinidade de hidroxicarbonato de zinco obtido via precipitação homogênea: influência dos ânions cloreto e nitrato

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Sociedade Brasileira de Química

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Article

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Abstract

The effects of chloride and nitrate anions and their respective concentrations, as well as urea presence, on solid phase morphologies were investigated. Zinc hydroxide carbonate was prepared by aging diluted zinc salt solution in presence of urea at 90ºC. Samples were identified by X-ray powder diffractograms showing the characteristic patterns of hydrozincite. The crystallinity was correlated with the concentrations of reagents. Spherulitic-type aggregates and single acicular particles were obtained from diluted chloride and nitrate solutions while porous aggregates of uniform size were formed from solutions with high chloride and urea concentrations.

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Keywords

zinc hydroxide carbonate, homogeneous precipitation, morphology, spherulites

Language

Portuguese

Citation

Química Nova. Sociedade Brasileira de Química, v. 23, n. 5, p. 627-631, 2000.

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Instituto de Química
IQAR
Campus: Araraquara


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