A Mono-Metallic Pd(II)-Cage Featuring Two Different Polar Binding Sites

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Title:	A Mono-Metallic Pd(II)-Cage Featuring Two Different Polar Binding Sites
Author:	Escobar, Luis; Villarón, David; Escudero-Adán, Eduardo C.; Ballester, Pablo
Abstract:	The tetra-α isomer of a super aryl-extended tetra-pyridyl calix[4]pyrrole self-assembles into a mono-metallic Pd(II)-cage featuring two different and converging polar binding sites. Mono- and di-topic polar guests are bound reversibly in the cage. A mechanism for guest exchange in the cage complexes is proposed.
Publication date:	2018-12-12
Subject(s):	54
Rights:	L'accés als continguts d'aquest document queda condicionat a l'acceptació de les condicions d'ús establertes per la següent llicència Creative Commons:http://creativecommons.org/licenses/by-nc-nd/4.0/
Pages:	604 p.
Document type:	Article Article - Accepted version
DOI:	10.1039/C8CC09195A
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