Journal Article FZJ-2022-01762

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A route towards high‐efficiency silicon heterojunction solar cells

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2022
Wiley Chichester

Progress in photovoltaics 30(4), 384 - 392 () [10.1002/pip.3493]

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Abstract: In this work, we propose a route to achieve a certified efficiency of up to 24.51% for silicon heterojunction (SHJ) solar cell on a full-size n-type M2 monocrystalline-silicon Cz wafer (total area, 244.53 cm2) by mainly improving the design of the hydrogenated intrinsic amorphous silicon (a-Si:H) on the rear side of the solar cell and the back reflector. A dense second intrinsic a-Si:H layer with an optimized thickness can improve the vertical carrier transport, resulting in an improved fill factor (FF). In order to reduce the plasmonic absorption at the back reflector, a low-refractive-index magnesium fluoride (MgF2) is deposited before the Ag layer; this leads to an improved gain of short circuit current density (Jsc). In total, together with MgF2 double antireflection coating and other fine optimizations during cell fabrication process, ~1% absolute efficiency enhancement is finally obtained. A detailed loss analysis based on Quokka3 simulation is presented to confirm the design principles, which also gives an outlook of how to improve the efficiency further.

Classification:

Contributing Institute(s):
  1. Photovoltaik (IEK-5)
Research Program(s):
  1. 1213 - Cell Design and Development (POF4-121) (POF4-121)
  2. Verbundvorhaben: Street - Einsatz von hocheffizienten Solarzellen in elektrisch betriebenen Nutzfahrzeugen; Teilvorhaben: Herstellung und Entwicklung von (0324275E) (0324275E)
  3. Verbundvorhaben: TuKaN - Tunnelkontakte auf N-Typ: für die Metallisierung mit Siebdruck, Teilvorhaben: Herstellung von Solarzellen mit passivierendem Tunnelkontakt und funktionalen Schichten aus katalytischer und plasmaunterstützter chemischer Gasphasenab (0324198D) (0324198D)
  4. Touch - Technologie- und Charakterisierungsplattform für die Entwicklung von hoch-effizienten Silizium-Heterostruktursolarzellen (0324351) (0324351)

Appears in the scientific report 2022
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Medline ; Creative Commons Attribution-NonCommercial-NoDerivs CC BY-NC-ND 4.0 ; OpenAccess ; Clarivate Analytics Master Journal List ; Current Contents - Engineering, Computing and Technology ; Current Contents - Physical, Chemical and Earth Sciences ; DEAL Wiley ; Essential Science Indicators ; SCOPUS ; Science Citation Index Expanded ; Web of Science Core Collection
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 Record created 2022-03-25, last modified 2023-03-03