A blue to highly transmissive soluble electrochromic polymer based on poly(3,4-propylenedioxyselenophene) with a high stability and coloration efficiency

Date

2011-01-01

Author

Ozkut, Merve Icli
Atak, Samed
Önal, Ahmet Muhtar
CİHANER, ATİLLA

Metadata

Show full item record

This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

Item Usage Stats

128
views

0
downloads

The optical and electrochemical properties of a regioregular and soluble alkylenedioxyselenophene-based electrochromic polymer, namely poly(3,3-didecyl-3,4-dihydro-2H-selenopheno[3,4-b][1,4] dioxepine (PProDOS-C-10), which is synthesized by electrochemical polymerization, are highlighted. It is noted that this unique polymer has a low band gap (1.58 eV) and is exceptionally stable under ambient atmospheric conditions. Polymer films retain 97% of their electroactivity after 40 000 cycles. The percentage transmittance of a PProDOS-C10 film was found to be 56.4% at 638 nm and 55.8% at 700 nm. Furthermore, this novel soluble PProDOS-C10 polymer shows an electrochromic behavior: a color change from pure blue to a highly transparent state in a low switching time (1.0 s) during oxidation, with high coloration efficiencies (328 cm 2 C-1 at 638 nm and 319 cm(2) C-1 at 700 nm) when compared to its thiophene analogue.

Subject Keywords

Donor-acceptor approach, Anodic region , Tungsten-oxide, Charge capacity, Oxygen-electrode, Conducting polymers, Conjugated polymers, Polyselenophene films, Dioxythiophene polymers, Poly(3,4-Alkylenedioxythiophene) derivatives

URI

https://hdl.handle.net/11511/37481

Journal

JOURNAL OF MATERIALS CHEMISTRY

DOI

https://doi.org/10.1039/c0jm04285d

Collections

Department of Chemistry, Article

Suggestions

OpenMETU
Core

A unique processable green polymer with a transmissive oxidized state for realization of potential RGB-based electrochromic device applications Günbaş, Emrullah Görkem; Toppare, Levent Kamil (2008-07-23) Realization of commercial RGB-based polymer electrochromic-device applications can only be achieved by processable materials that possess three complementary colors in the reduced state and are transparent in the oxidized state. This report highlights the synthesis of the first processable green polymer with a transmissive oxidized state. The polymer revealed superior optical contrast in the visible region with fast switching times and robust stability. Hence, this material is the outstanding candidate for ...
A NEW DIFUNCTIONAL ANIONIC INITIATOR SOLUBLE IN NONPOLAR-SOLVENTS NUGAY, T; KUCUKYAVUZ, S (Wiley, 1992-01-01) The reaction between 1,5-diethenylnaphthalene and sec-butyllithium produces a new difunctional organolithium initiator which is soluble in non-polar solvents and effective in the synthesis of styrene-isoprene-styrene triblock copolymer. Monomodal molecular weight distributions are observed for block copolymers and styrene homopolymers. The microstructure of polyisoprene blocks is similar to those polymers initiated by butyllithium in the same solvent.
High optical transparency in all redox states: Synthesis and characterization of benzimidazole and thieno[3,2-b]thiophene containing conjugated polymers Zaifoglu, Buket; Sendur, Merve; Unlu, Naime Akbasoglu; Toppare, Levent Kamil (2012-12-15) The synthesis of a novel monomer based on benzimidazole and thieno[3,2-b]thiophene moieties, 4'-tert-butyl-4,7-di(thieno[3,2-b]thiophen-2-yl)spiro[benzo[d]imidazole-2,1'-cyclohexane] (TTBI), and its electrochemical polymerization are reported. Electrochemical and spectroelectrochemical studies of the polymer were investigated. The high optical transparency and low coloration efficiency during oxidation and reduction processes make the polymer a great candidate for hole-injection layers in light-emitting dio...
A new p and n dopable selenophene derivative and its electrochromic properties Ardahan, Gülben; Toppare, Levent Kamil; Department of Chemistry (2008) A novel electrically conducting polymer, poly(2-dodecyl-4,7-di(selenophen-2-yl)benzotriazole) (Poly(SBT)), containing selenophene as a strong donor and benzotriazole as a strong acceptor group was synthesized by electrochemical polymerization. Homopolymerization and copolymerization ( in the presence of 3,4-ethylenedioxythiophene (EDOT) ) was achieved in acetonitrile/ dichloromethane(95/5 v/v) with 0.1M tetrabutylammonium hexafluorophosphate (TBAPF6). The electrochemical and optical properties of homopolyme...
A neutral state yellow to navy polymer electrochrome with pyrene scaffold Icli-Ozkut, Merve; Oztas, Zahide; Algi, Fatih; CİHANER, ATİLLA (Elsevier BV, 2011-09-01) A new pyrene based soluble polymer, namely poly(3,3-didecyl-6-(1-(3,3-didecyl-3,4-dihydro-2H-thieno[3,4-b][1,4] dioxepin-6-yl) pyren-6-yl)-3,4-dihydro-2H-thieno[3,4-b][1,4] dioxepine), P5, which is synthesized by both chemical and electrochemical methods, is highlighted. The polymer shows both electrochromic and fluorescent properties (the emission of yellow (545 nm) and yellowish green light (524 nm) in solid state and in THF solution, respectively). It is noteworthy that P5 has a specific optical band gap...

Citation Formats

M. I. Ozkut, S. Atak, A. M. Önal, and A. CİHANER, “A blue to highly transmissive soluble electrochromic polymer based on poly(3,4-propylenedioxyselenophene) with a high stability and coloration efficiency,” JOURNAL OF MATERIALS CHEMISTRY, pp. 5268–5272, 2011, Accessed: 00, 2020. [Online]. Available: https://hdl.handle.net/11511/37481.