Trimethyl 4,4′,4′′-(ethene-1,1,2-triyl)tribenzoate

Date

2020-03-01

Author

Lesley, Melvin J
Özhan, Koray
Sung, Herman H-y
Williams, Ian D

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The title compound, C26H22O6, is formed as the major product from the reaction between syn-1,2-bis(pinacolatoboron)-1,2-bis(4-methylcarboxyphenyl)ethene and excess methyl 4-iodobenzoate in basic DMSO using a palladium catalyst at 80°C via Suzuki coupling followed by protodeboronation. Crystals were grown by slow evaporation of a hexanes solution at room temperature.

Subject Keywords

Crystal structure, Protodeboronation, Suzuki coupling

URI

http://scripts.iucr.org/cgi-bin/paper?S2414314620004174
https://hdl.handle.net/11511/71144

Journal

IUCrData

DOI

https://doi.org/10.1107/S2414314620004174

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Graduate School of Marine Sciences, Article

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Citation Formats

M. J. Lesley, K. Özhan, H. H.-y. Sung, and I. D. Williams, “Trimethyl 4,4′,4′′-(ethene-1,1,2-triyl)tribenzoate,” IUCrData, pp. 0–0, 2020, Accessed: 00, 2021. [Online]. Available: http://scripts.iucr.org/cgi-bin/paper?S2414314620004174.