Unambiguous identification of 17O containing ozone isotopomers for symmetry 
selective detection

Tuzson, Béla; Janssen, Christof

doi:10.1080/10256010500503130

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Unambiguous identification of ¹⁷O containing ozone isotopomers for symmetry selective detection

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Tuzson, Béla
Prof. Konrad Mauersberger, Emeriti, MPI for Nuclear Physics, Max Planck Society;

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Janssen, Christof
Prof. Konrad Mauersberger, Emeriti, MPI for Nuclear Physics, Max Planck Society;

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Citation

Tuzson, B., & Janssen, C. (2006). Unambiguous identification of ¹⁷O containing ozone isotopomers for symmetry selective detection. Isotopes in Environmental and Health Studies, 42(1), 67-75. doi:10.1080/10256010500503130.

Cite as: https://hdl.handle.net/11858/00-001M-0000-0011-8090-B

Abstract

Symmetry selective detection of the ¹⁷O containing ozone isotopomers ¹⁶O¹⁶O¹⁷O and ¹⁶O¹⁷O¹⁶O requires the unambiguous identification of absorption lines.We report high resolution tuneable diode laser spectrometer measurements of ¹⁷O containing ozone isotopomers in the R-branch of the υ3 band and present a purely experimental technique that discriminates between ¹⁶O¹⁶O¹⁷O and ¹⁶O¹⁷O¹⁶O. Around 1040 cm^-1, differences in line positions of ¹⁶O¹⁷O¹⁶O upto 4×10^-3 cm^-1 between our measurements and present spectroscopic database records (HITRAN 2004) are found.