Synthesis of hydroquinone-, biphenol-, and binaphthol-containing aza 
macroheterocycles via regioselective hydroformylation and reductive amination

Angelovski, G; Eilbracht, P

doi:10.1016/j.tet.2003.08.012

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Synthesis of hydroquinone-, biphenol-, and binaphthol-containing aza macroheterocycles via regioselective hydroformylation and reductive amination

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https://www.sciencedirect.com/science/article/pii/S004040200301250X
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Citation

Angelovski, G., & Eilbracht, P. (2003). Synthesis of hydroquinone-, biphenol-, and binaphthol-containing aza macroheterocycles via regioselective hydroformylation and reductive amination. Tetrahedron, 59(41), 8265-8274. doi:10.1016/j.tet.2003.08.012.

Cite as: https://hdl.handle.net/11858/00-001M-0000-0013-DD86-3

Abstract

Rhodium(I) catalyzed regioselective hydroformylation of diolefins and
subsequent reductive amination of the dialdehydes in the presence of
α,ω-diamines is applied to azamacroheterocyclic ring synthesis

Rhodium(I) catalyzed regioselective
hydroformylation of diolefins and subsequent reductive amination of the
dialdehydes in the presence of α,ω-diamines is applied to
azamacroheterocyclic ring synthesis. Starting from aromatic diallyl ethers of
hydroquinone, biphenol and binaphthol 2028 membered macroheterocycles were
obtained in up to 78 yield.