Kinetic 15N-CPMAS-NMR study of a double proton transfer in a crystalline 
malonaldehyde diimine derivative

Limbach, Hans−Heinrich; Wehrle, Bernd; Zimmermann, Herbert; Kendrick, Ray D.; Yannoni, Costantino S.

doi:10.1002/anie.198702471

Item

ITEM ACTIONSEXPORT

Add to Basket

Local TagsRelease HistoryDetailsSummary

Released

Journal Article

Kinetic 15N-CPMAS-NMR study of a double proton transfer in a crystalline malonaldehyde diimine derivative

MPS-Authors

/persons/resource/persons128263

Zimmermann, Herbert
Department of Molecular Physics, Max Planck Institute for Medical Research, Max Planck Society;
Department of Biomolecular Mechanisms, Max Planck Institute for Medical Research, Max Planck Society;
Zimmermann Group, Max Planck Institute for Medical Research, Max Planck Society;
Emeritus Group Biophysics, Max Planck Institute for Medical Research, Max Planck Society;

External Resource

http://onlinelibrary.wiley.com/doi/10.1002/anie.198702471/epdf
(Any fulltext)

https://doi.org/10.1002/anie.198702471
(Any fulltext)

Fulltext (restricted access)

There are currently no full texts shared for your IP range.

Fulltext (public)

There are no public fulltexts stored in PuRe

Supplementary Material (public)

There is no public supplementary material available

Citation

Limbach, H., Wehrle, B., Zimmermann, H., Kendrick, R. D., & Yannoni, C. S. (1987). Kinetic 15N-CPMAS-NMR study of a double proton transfer in a crystalline malonaldehyde diimine derivative. Angewandte Chemie, International Edition in English, 26(3), 247-248. doi:10.1002/anie.198702471.

Cite as: https://hdl.handle.net/11858/00-001M-0000-0019-AE85-3

Abstract

Solid state effects gave rise to an energy difference of about 4 kJ mol−1 between the tautomers 1 and 2. This could be deduced from dynamic 15N-NMR spectra, which were recorded under the conditions of cross-polarization and of sample rotation about the magic angle.