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Journal Article

{4,4′,6,6′-Tetra­bromo-2,2′-[(2,2-di­methyl­propane-1,3-di­yl)bis­­(nitrilo­methanylyl­­idene)]diphenolato}copper(II).

MPS-Authors
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Kia,  R.
Research Group of Structural Dynamics of (Bio)Chemical Systems, MPI for Biophysical Chemistry, Max Planck Society;

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2371784.pdf
(Publisher version), 352KB

Supplementary Material (public)

2371784_Suppl_1.cif
(Supplementary material), 17KB

2371784_Suppl_2.hkl
(Supplementary material), 125KB

Citation

Kargar, H., Kia, R., Haghsenas, M., & Tahir, M. N. (2012). {4,4′,6,6′-Tetra­bromo-2,2′-[(2,2-di­methyl­propane-1,3-di­yl)bis­­(nitrilo­methanylyl­­idene)]diphenolato}copper(II). Acta Crystallographica Section E, 68(4): m392.


Cite as: https://hdl.handle.net/11858/00-001M-0000-002C-1A9E-8
Abstract
In the title compound, [Cu(C19H16Br4N2O2)], the CuII ion and the substituted C atom of the diamine fragment lie on a crystallographic twofold rotation axis. The geometry around the CuII ion is distorted square-planar, which is defined by the N2O2 donor atoms of the coordinated Schiff base ligand. The dihedral angle between the symmetry-related substituted benzene rings is 25.33 (14)°. The crystal structure is stabilized by an inter­molecular π–π inter­action [centroid–centroid distance = 3.8891 (18) Å].