Azine Activation via Silylium Catalysis

Obradors, Carla; List, Benjamin

doi:10.1021/jacs.1c03257

Item

ITEM ACTIONSEXPORT

Add to Basket

Local TagsRelease HistoryDetailsSummary

Released

Journal Article

Azine Activation via Silylium Catalysis

MPS-Authors

/persons/resource/persons226594

Obradors, Carla
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

/persons/resource/persons58764

List, Benjamin
Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society;

External Resource

No external resources are shared

Fulltext (restricted access)

There are currently no full texts shared for your IP range.

Fulltext (public)

Azine Activation via Silylium Catalysis.pdf
(Publisher version), 832KB

Supplementary Material (public)

There is no public supplementary material available

Citation

Obradors, C., & List, B. (2021). Azine Activation via Silylium Catalysis. Journal of the American Chemical Society, 143(18), 6817-6822. doi:10.1021/jacs.1c03257.

Cite as: https://hdl.handle.net/21.11116/0000-0008-EEA8-F

Abstract

Practical, efficient, and general methods for the diversification of N-heterocycles have been a recurrent goal in chemical synthesis due to the ubiquitous influence of these motifs within bioactive frameworks. Here, we describe a direct, catalytic, and selective functionalization of azines via silylium activation. Our catalyst design enables mild conditions and a remarkable functional group tolerance in a one-pot setup.