Characterization by X‐ray <scp>μCT</scp> of the air‐filled porosity of an agricultural soil at different matric potentials

To describe various important soil processes like the release of greenhouse gases or the proliferation of microorganisms, it is necessary to assess quantitatively how the geometry and in particular the connectivity of the air-filled pore space of a soil evolves as it is progressively dried. The availability of X-ray computed microtomography (μCT) images of soil samples now allows this information to be obtained directly, without having to rely on the interpretation of macroscopic measurements using capillary theory, as used to be the case. In this general context, we present different methods to describe quantitatively the configuration of the air-filled pore space in 3D μCT images of 20 separate samples of a loamy soil equilibrated at different matric potentials. Even though measures using μCT on such multi-scale materials strongly depends on image resolution, our results show that in general, soil samples most often behave as expected, e.g., connectivity increases with higher negative matric potential, while tortuosity decreases. However, simple correlations could not be found between the evolution of quantitative descriptors of the pore space at the different matric potentials and routinely measured macroscopic soil parameters. A statistical analysis of all soil samples concurrently confirmed this lack of correspondence.