Reverse atom-transfer radical polymerization at room temperature

[en] This paper aims at reporting on the living/controlled radical polymerization of methyl methacrylate initiated with the benzoyl peroxide (BPO)/CuIX (X=Br,Cl)/2,2'-bipyridine (bpy) redox system at room temperature. No control is observed for the polymerization conducted in bulk and in toluene, whereas a polymer with predetermined molecular weight and rather narrow molecular weight distribution is formed in butanone. The solvent has thus a decisive effect on the reverse atom-transfer radical polymerization of methyl methacrylate initiated with the BPO/CuIX (X = Br,Cl)/bpy ternary system at 25°C.

Research Center/Unit :

Center for Education and Research on Macromolecules (CERM)

Disciplines :

Chemistry
Materials science & engineering

Author, co-author :

Wang, Wenxin; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Yan, Deyue; Shanghai Jiao Tong University, College of Chemistry and Chemical Technology, China

Jiang, Xuling; Shanghai Jiao Tong University, College of Chemistry and Chemical Technology, China

Detrembleur, Christophe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Lecomte, Philippe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Jérôme, Robert ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Language :

English

Title :

Reverse atom-transfer radical polymerization at room temperature

Publication date :

March 2001

Journal title :

Macromolecular Rapid Communications

ISSN :

1022-1336

eISSN :

1521-3927

Publisher :

Wiley-V C H Verlag Gmbh, Weinheim, Germany

Volume :

Issue :

Pages :

439-443

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

http://www3.interscience.wiley.com/cgi-bin/fulltext/78505179/PDFSTART

Funders :

BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique

Available on ORBi :

since 22 January 2009

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Bibliography

Otsu T., Yoshida M. Makromol. Chem., Rapid Commun. 1982, 3:127.
Otsu T., Yoshida M. Makromol. Chem., Rapid Commun. 1982, 3:133.
Georges M.K., Veregin R.P.N., Kazmaier P.M., Hamer G.K. Macromolecules 1993, 26:5316.
Wayland B.B., Poszmik G., Mukerjee S.L., Fryd M. J. Am. Chem. Soc. 1994, 116:7943.
Greszta D., Mardare D., Matyjaszewski K. Macromolecules 1994, 27:638.
Matyjaszewski K., Gaynor S., Wang J.S. Macromolecules 1995, 28:2093.
Wang J.S., Matyjaszewski K. J. Am. Chem. Soc. 1995, 117:5614.
Solomon D.H., Rizzardo E., Cacioli P. Chem. Abstr. , U.S. 4,581,429; 1986, 102:2213359.
Chiefari J., Chong Y.K.B., Ercole F., Krstina J., Jeffery J., Le T.P.T., Mayadunne R.T., Meijs G.F., Moad C.L., Moad G., Rizzardo E., Thang S.H. Macromolecules 1998, 31:5559.
Asscher M., Vofsi D. J. Chem. Soc. 1963, 1887.
Wang J.S., Matyjaszewski K. Macromolecules 1995, 28:7901.
Kato M., Kamigaito M., Sawamoto M., Higashimura T. Macromolecules 1995, 28:1721.
Percec V., Barboiu B. Macromolecules 1995, 28:7970.
Granel G., Dubois P., Jérôme R., Teyssié P. Macromolecules 1996, 29:8576.
Haddleton D.M., Jasieczek C.B., Hannon M.J., Shooter A.J. Macromolecules 1997, 30:2190.
Haddleton D.M., Kukulj D., Duncalf D.J., Heming A.M., Shooter A.J. Macromolecules 1998, 31:5201.
Xia J., Gaynor S., Matyjaszewski K. Macromolecules 1998, 31:5958.
Takahashi H., Ando T., Kamigaito M., Sawamoto M. Macromolecules 1999, 32:6461.
Lecomte Ph., Drapier I., Dubois Ph., Teyssié Ph., Jérôme R. Macromolecules 1998, 31:545.
Wang X., Luo N., Ying S. Polymer 1999, 40:4157.
Wang J.S., Matyjaszewski K. Macromolecules 1995, 28:7572.
Xia J.H., Matyjaszewski K. Macromolecules 1997, 30:7692.
Moineau G., Dubois Ph., Jérôme R., Senninger T., Teyssié Ph. Macromolecules 1998, 31:545.
Wang W., Dong Z., Xia P., Yan D. Macromol. Rapid Commun. 1998, 19:647.
Wang W., Tu W., Zhang B., Yan D., Tai H. China Synthesis Rubber Industry 1999, 22(1):47.
Zhu S., Wang W., Tu W., Yan D. Acta Polym. 1999, 50:267.
Yan D., Wang W., Tu W. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1999, 40(2):358.
Wang W., Yan D. ACS Symp. Ser. 2000, 768:263.
Xia J., Matyjaszewski K. Macromolecules 1999, 32:5199.
Yu T. Polymer Experimental Technology , G. Cheng, Ed., Polymer Science Department of Fudan University, Fudan Publishing Company Shanghai; 1996, 361.

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