self-assembly in solution; micelle; network; stimuli responsive micelle
Abstract :
[en] The triblock copolymer PS-b-P2VP-b-PEO undergoes simultaneous micellization and gelation, leading to high-storage-modulus materials that have fast responses to pH value, temperature, ionic strength, and shearing. The gel has a hierarchical structure with spherical core-shell-corona micelles, which, in turn, pack closely into an ordered cubic structure.
Research Center/Unit :
Center for Education and Research on Macromolecules (CERM)
Disciplines :
Chemistry Materials science & engineering
Author, co-author :
Willet, Nicolas ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Gohy, Jean-François; Université catholique de Louvain (UCL) > Chemistry of Inorganic and Organic Materials Unit (CMAT)
Lei, Liangcai; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Heinrich, Martine; Institut fEr FestkGrperforschung (IFF), Forschungszentrum Jülich, Germany)
Auvray, Loïc; CEA Saclay, France > Laboratoire Léon Brillouin (LLB)
BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique CE - Commission Européenne ESF - European Science Foundation
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